Spontaneous formation of dye-functionalized gold nanoparticles using reverse micellar systems.

نویسندگان

  • Masaki Takahashi
  • Shuhei Ohno
  • Norifumi Fujita
  • Tetsuya Sengoku
  • Hidemi Yoda
چکیده

Detailed exploratory and mechanistic investigations on spontaneous formation of dye-functionalized gold nanoparticles (GNPs) using dye-based reverse micellar systems are described in this publication. The accumulated results from spectroscopic and microscopic investigations demonstrated that water molecules confined within nanoscopic enclosure of the self-assembled reverse micelles played critical role in the redox processes of aurate ions to produce GNPs, which are assumed to have approximately constant size distributions. The resulting dye-functionalized GNPs were found to offer their absorption and fluorescence emission tunability by changing the medium polarity as well as to exhibit excellent film-forming properties to give optically homogeneous polystyrene thin films. These key findings in addition to broad applicability of the self-assembling process with a variety of dye analogues have led to a conclusion that the protocol presented here serves as a versatile synthetic method to provide a potential convenience for future development of new organic-inorganic hybrid nanomaterials.

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عنوان ژورنال:
  • Journal of colloid and interface science

دوره 356 2  شماره 

صفحات  -

تاریخ انتشار 2011